STUDY OF RADIATION-THERMAL DECOMPOSITION OF WATER IN THENANO-SI/H2O SYSTEM USING FOURIER INFRARED SPECTROSCOPY
DOI:
https://doi.org/10.58225/sw.2025.1-113-116Keywords:
gamma radiation, nanoparticle, radiolysis, Fourier infrared spectrometerAbstract
The effect of ionizing radiation on nanoparticles can change the chemical and physical properties of materials. The study of these processes by means of Fourier infrared spectroscopy leads to a better understanding of the behavior of nanomaterials in the radiation environment and the development of new fields of application. This research is important from both scientific and practical point of view. Radiation-thermal under the influence of thermal and ionizing rays (60Co, P=18.17 rad/sec, T=300K, 373, 473, 573, 623 and 673K) in the systems created in Si/H2O (50, 100, 300-500 nm) Fourier infrared spectroscopy was used to study the products and intermediates obtained during the processes. The formation of intermediate - active products (hydrides and hydroxyl groups) during water splitting at room temperature (T=300K) in the nano-Si/H2O heterosystem under the influence of ionizing rays was determined.
- Views
- 202
- Downloads
- 158
References
1. Agayev, T. N., Gadzhieva, N. N., Melikova, S. Z., İmanova, G. T., & Faradjzade, I. A. (2018). An IR spectroscopic study of the gamma radiation on the nano-ZrO₂ + nano-SiO₂ + H₂O systems. Protection of Metals and Physical Chemistry of Surface, 54(5), 813-816.
2. Agayev, T. N., Gadzhieva, N. N., & Melikova, S. Z. (2018). Fourier transform IR spectroscopic study of nano-ZrO₂ + nano-SiO₂ + H₂O systems upon the action of gamma radiation. Journal of Applied Spectroscopy, 85(2), 365-369. Elmi əsərlər, Tətbiqi riyaziyyat və mexanika Scientific works, Applied mathematics and mechanics, 2025, N1.116
3. Агаев, Т. Н., Гаджиева, Н. Н., & Меликова, С. З. (2017). Радиационное разложение воды в системе n-ZrO₂ + n-SiO₂ + H₂O. In Международный форум «Ядерная наука и технологии», посвященный 60 летию Института Ядерной физики (pp. 96-98).
4. Bashirova, S. M., Jafarov, Y. D., & Aliyev, S. M. (2017). Dependence of the yield of molecular hydrogen obtained from radiation-heterogeneous decomposition of water on particle size of silica and filling rate of particle surface of water in Si + H₂O system by the influence of gamma-quanta. Azerbaijan National Academy of Sciences Institute of Radiation Problems, Journal of Radiation Researches, 4(2), 16-23.
5. Джафаров, Я. Д., Баширова, С. М., Гарибов, А. А., & Эюбов, К. Т. (2019). Получение молекулярного водорода, образованного термическим и радиационно-термическим превращением воды в системе нано-Si + H₂O. Вопросы атомной науки и техники (ВАНТ),Национальный научный центр "Харьковский физико-технический институт", 1, 55-60.
6. Баширова, С. М. (2019). Влияние массы кремния на процесс радиолиза, протекающего при воздействии -квантов на суспензионную систему нано-Si/H₂O. In EurasiaScience XXV Международная научно-практическая конференция (pp. 3-4). Научно-издательский центр "Актуальность.РФ".
7. Bashirova, S. (2024). Fourier Infrared Spectroscopy study of radiation-thermal water decomposition in Nano-Si/H₂O system. In 21st international conference on defects in insulating materials –-ICDIM 2024, L.N. Gumilyov Eurasian National University, 19-23 August 2024.
8. Jafarov, Y. D., Bashirova, S. M., Mardanov, I. J., & Imanova, G. T. (2023). Obtaining molecular hydrogen from water radiolysis in the nano-SiO₂ (d = 20 nm) / H₂O system under the influence of γ-quanta. Cambridge University Press, Experimental Results UK, 1-11.
9. Qəribov, A. A., Ağayev, T. N., Bəşirova, S. M., İmanov, G. T., Əliyev, A. Q., & Cəfərov, Y. D. (2024). Mechanism of hydrogen production in the processes of radiation-heterogeneous splitting of water with the presence of nano-metal and Nano-MeO₁. East European Journal of Physics, 460-475.
10. Cəfərov, Y. D., Bəşirova, S. M., İmanova, G. T., & Əliyev, S.M. (2023). Study of molecular hydrogen in the nano-SiO₂ / H₂O system under the influence of γ-quanta. In X International Scientific Conference "Actual Problems of Solid State Physics" (APSSP-2023), Belarus, 22-26 May 2023 (p.358).
11. Bashirova, S. M. (2022). The impact of silicon mass on the radiolysis process occurring under the influence of gamma-quanta on nano-Si / H₂O suspension system. In IV International Scientific Forum "NUCLEAR SCIENCE AND TECHNOLOGIES" dedicated to the 65th anniversary of the Institute of Nuclear Physics (pp. 106). Institute of Nuclear Physics Ministry of Energy of the Republic of Kazakhstan.
12. Bəşirova, S. M., & Cəfərov, Y. D. (2016). Si + H₂O sistemində suyun radiolizi prosesində kütlə effekti. Azərbaycan Milli Aerokosmik Agentliyinin xəbərləri, 2(19), 52-60.
13. Theophanides, T. (2012). Infrared Spectroscopy- Materials Science, Engineering and Technology, Introduction to Infrared Spectroscopy. National Technical University of Athens
Published
Issue
Section
License
Copyright (c) 2025 Bashirova Sevinj (Author)

This work is licensed under a Creative Commons Attribution 4.0 International License.


